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New coating formulation based on synthesized benzodiazepine derivatives as double function additives for industrial application

Nashwa Mostafa Saleh (Department of Chemistry, Faculty of Science for Girls in Cairo, Al-Azhar University, Nasr City, Egypt)
Maha Mohammed Elsawy (Department of Chemistry, Faculty of Science for Girls in Cairo, Al-Azhar University, Nasr City, Egypt)
Hamada Abd El-Wahab (Department of Chemistry, Faculty of Science, Al-Azhar University, Cairo, Egypt)
Salem Salah Salem (Department of Microbiology, Faculty of Science, Al-Azhar University, Cairo, Egypt)
Nour El-Din Abd El-Sattar (Faculty of Science, Ain Shams University, Cairo, Egypt)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 14 October 2021

Issue publication date: 8 December 2022

174

Abstract

Purpose

The purpose of this study is to develop a new protective coating formulation for industrial use, using benzodiazepine derivatives as double function additives.

Design/methodology/approach

Benzodiazepine’s derivatives of types (3–5) were prepared and confirmed by infrared, Mass, 1H-Proton nuclear magnetic resonance (NMR) and 13C NMR spectra. The synthesized compound was physically incorporated in the alkyd paint formulation by pebble mill grinding until all particulates are smaller than 20 ums. The prepared coatings were applied by air spray on steel panels. The physical, mechanical characteristics, corrosion resistance and antimicrobial test of the prepared coatings were studied to evaluate the prepared compounds drawbacks.

Findings

The results of the mechanical and physical properties of the paint formulation revealed that the paint formulation incorporating benzodiazepines derivatives 3–5 performed best and improved corrosion-resistance and antibacterial activity tests.

Research limitations/implications

In alkyd paint, heterocyclic compounds are the most used antibacterial additives. Other functionalities of these compounds, such as corrosion inhibitors, might be studied to see if they are suited for these applications.

Practical implications

Because of the activity of various benzodiazepine derivatives, which may be attributable to the presence of some function groups such as sulfonamide aromatic amino NH2 group, and elements such as Sulphur, Nitrogen, Chlorine, in its chemical structure. As a result, paint compositions including these compounds as additives can be used as dual-purpose paint and for a variety of industrial applications.

Originality/value

The research demonstrates how a low-cost paint composition based on synthesized benzodiazepine derivatives 3–5 may be used as a dual-function paint for industrial use.

Keywords

Acknowledgements

The authors would like to thank prof. Ashraf M. El-Saeed, Professor of applied chemistry, Egyptian petroleum research institute, Egypt, Cairo, for his helping.

Citation

Mostafa Saleh, N., Elsawy, M.M., Abd El-Wahab, H., Salem, S.S. and Abd El-Sattar, N.E.-D. (2022), "New coating formulation based on synthesized benzodiazepine derivatives as double function additives for industrial application", Pigment & Resin Technology, Vol. 51 No. 6, pp. 581-599. https://doi.org/10.1108/PRT-06-2021-0061

Publisher

:

Emerald Publishing Limited

Copyright © 2021, Emerald Publishing Limited

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