Preparation and properties of polyimide/Fe₃O₄ composite foams

Abstract

Purpose

This paper aims to develope the electromagnetic interference shielding materials with high performance. To develop advanced polymer-based electromagnetic interference shielding materials with rather high temperature stability, good processability and moderate mechanical properties, the authors chose the polyimide (PI) foam as matrix and ferriferrous oxide (Fe₃O₄) as fillers to prepare the composite foams with lightweight and rather good electromagnetic interference shielding performance.

Design/methodology/approach

Some polyimide nanocomposite foams with Fe₃O₄ as fillers have been prepared by in situ dispersion and foaming with pyromellitic dianhydride (PMDA) and isocyanate (PAPI) as raw materials and water as foaming agent. By varying the Fe₃O₄ contents, a series of PI/Fe₃O₄ nanocomposite foams with fine microstructures and high thermal stability were obtained. The structure and performances of nanocomposite foams were examined, and the effects of Fe₃O₄ on the microstructure and properties of composite foams were investigated.

Findings

This work demonstrates that PI/Fe₃O₄ foams could be fabricated by thermally treating the polyimide foam intermediates with Fe₃O₄ nanoparticles through a blending reaction of precursors. The final PI/Fe₃O₄ composite foams maintained the excellent thermal property and showed a super paramagnetic behaviour, which has a positive effect on the improvement of electromagnetic shielding performance.

Research limitations/implications

In this paper, the effects of Fe₃O₄ on the performances of PI/Fe₃O₄ composite foam were reported. It provided an effective methodology for the preparation of polymer/Fe₃O₄ nanocomposite foams, which hold great promise towards the potential application in the areas of electromagnetic shielding materials.

Originality/value

A series of PI/Fe₃O₄ composite foams with different contents of Fe₃O₄ were prepared by blending reaction of the precursors. The effects of Fe₃O₄ on the structures and properties of PI/Fe₃O₄ composite foam were discussed in detail.

Citation

Weng, L., Wang, T., Ju, P.-H. and Liu, L.-Z. (2018), "Preparation and properties of polyimide/Fe₃O₄ composite foams", Pigment & Resin Technology, Vol. 47 No. 2, pp. 173-179. https://doi.org/10.1108/PRT-01-2017-0006