Hot corrosion behaviour of CNT-reinforced ZrO₂-Y₂O₃ composite coatings on boiler tube steel at 900°C

Abstract

Purpose

In Indian thermal power plants, the main cause of boiler tube failure is the presence of molten sulphates and vanadates, which deteriorate the tube material at high temperatures. To combat the hot corrosion failure of metals, thermal spray technology is adopted. This study aims to investigate and study the effect of hot corrosion behaviour of carbon nanotube (CNT)-reinforced ZrO₂-Y₂O₃ composite coatings on T-91 boiler tube steel in a molten salt environment at 900 °C for 50 cycles.

Design/methodology/approach

A plasma spray technique was used for development of the coatings. The samples were exposed to hot corrosion in a silicon tube furnace at 900 °C for 50 cycles. After testing, the test coupons were analysed by X-ray diffraction, scanning electron microscopy/energy dispersive spectroscopy and cross-sectional analysis techniques to aid understanding the kinetics of the corrosion reaction.

Findings

CNT-based reinforced coatings showed lower weight gain along with the formation of protective oxide scales during the experimentation. Improvement in protection against hot corrosion was observed with increase in CNT content in the coating matrix.

Originality/value

It is pertinent to mention here that the high temperature behaviour of CNT-reinforced ZrO₂-Y₂O₃ composite on T-91 steel at 900°C temperature in molten salt environment has never been studied. Thus, the present research was conducted to provide useful results for the application of CNT-reinforced composite coatings at elevated temperature.

Citation

Kumar, S., Bhatia, R. and Singh, H. (2021), "Hot corrosion behaviour of CNT-reinforced ZrO₂-Y₂O₃ composite coatings on boiler tube steel at 900°C", Anti-Corrosion Methods and Materials, Vol. 68 No. 6, pp. 503-515. https://doi.org/10.1108/ACMM-12-2020-2412