Evaluation of Ni_0.5Zn_0.5Fe₂O₄ nanoparticles as anti-corrosion pigment in organic coatings for carbon steel

Abstract

Purpose

Inorganic oxide addition can be synergistically beneficial in organic coatings if it can impart anti-corrosion properties and also act as an additive to enhance physical and/or chemical properties. The aim of this study was to evaluate the anti-corrosion benefits of nano nickel zinc ferrite (NZF) in the polymer film.

Design/methodology/approach

The time-dependent anti-corrosion ability of NZF (0.12-1.0 per cent w/w NZF/binder), applied on API 5L X-80 carbon steel, was characterized by electrochemical techniques such as open circuit potential, electrochemical impedance spectroscopy, linear polarization resistance and potentiodynamic. Characterization of corrosion layer was done by removing coatings after 216 h of immersion in 3.5 per cent w/v NaCl. Optical microscopy, field emission scanning electron microscopy and X-ray diffraction techniques were used to characterize the corroded surface.

Findings

Corrosion measurements confirm the electrochemical activity by metallic cations on the steel surface during corrosion process which results in improvement of anti-corrosion properties of steel. Moreover, surface techniques show compact corrosion layer coatings and presence of different metallic oxide phases for nanocomposite coatings.

Originality/value

The suggested protection mechanism was explained by the leaching and precipitation of metallic ion on the corroded surface which in turn slowed down the corrosion activity. Furthermore, improvement in barrier properties of rubber-based coatings was confirmed by the enhanced pore resistance. This work indicates that along with a wide range of applications of NZF, anti-corrosion properties can be taken as an addition.

Citation

Chaudhry, A.U., Mittal, V., Hashmi, M.I. and Mishra, B. (2017), "Evaluation of Ni_0.5Zn_0.5Fe₂O₄ nanoparticles as anti-corrosion pigment in organic coatings for carbon steel", Anti-Corrosion Methods and Materials, Vol. 64 No. 6, pp. 644-653. https://doi.org/10.1108/ACMM-10-2016-1725