Influence of Mg²⁺substitution on the magnetic and electrical properties of Li‐Zn ferrite thick films synthesized with PVA matrix

Abstract

Purpose

The purpose of this paper is to investigate the effect of Mg²⁺substitution on the magnetic and electrical properties of Li_0.35−x Mg_2x Zn_0.3 Fe_2.35−xO₄ thick films synthesized with polyvinyl alcohol (PVA) matrix.

Design/methodology/approach

The nanoferrites Li_0.35−x Mg_2x Zn_0.3 Fe_2.35−xO₄ (x=0, 0.07, 0.14, 0.21, 0.28 and 0.35) were synthesized by chemical technique using aqueous solution of PVA (the matrix) and thick films were fabricated by screen printing technique. The DC magnetic hysteresis measurements, AC magnetic susceptibility and DC electrical resistivity were measured as a function of temperature.

Findings

The lattice parameter of thick film Li_0.35−x Mg_2x Zn_0.3 Fe_2.35−xO₄ (x=0, 0.07, 0.14, 0.21, 0.28 and 0.35) increases with the substitution of Mg²⁺ions for Li¹⁺and Fe³⁺. The surface morphology of the thick films showed the grain size increasing with Mg²⁺substitution till x=0.21 and then decreasing for the higher concentrations of magnesium. The magnetic moment n_B (μ_B) computed from the M_s obtained by extrapolation of the magnetization curve showed a gradual decrease with the composition till x=0.21, beyond which a sudden decrease was observed. The resistivity of the films at room temperature had variation with composition x, similar to that of magnetic moment. The activation energies ΔE_F and ΔE_P were found to vary with composition x of the ferrite system.

Originality/value

The paper reports, for the first time, the magnetic and electrical properties of fritless Li_0.35−xMg_2xZn_0.3Fe_2.35−xO₄ thick films using PVA polymer matrix. Up to x=0.21 (Mg²⁺), grain size increases and Curie temperature decreases beyond which reverse effect takes place.

Citation

Rendale, M.K., Kulkarni, S.D., Kulkarni, D.C. and Puri, V. (2011), "Influence of Mg²⁺substitution on the magnetic and electrical properties of Li‐Zn ferrite thick films synthesized with PVA matrix", Microelectronics International, Vol. 28 No. 1, pp. 58-65. https://doi.org/10.1108/13565361111097128